Charge Distributions and Chemical Effects: A New Approach to the Electronic Structure and Energy of Molecules


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The energy of a molecule can be studied with the help of quantum theory, a satisfactory approach because it involves only basic and clearly identified physical concepts. In an entirely different approach, the molecular energy can be broken down into individual contributions reflecting chemical bonds plus a host of subsidiary "effects", like y-gauche, skew pentane, ring-strain, etc., giving an overall picture in terms of topological characteristics. The latter approach can be successful, particularly if a sufficient number ...

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